Product ID:ETHANOL PROPRIETARY ANHY 509, 7430500
MSDS Date:12/22/1988
FSC:6850
NIIN:00N025213
MSDS Number: BMPHH

ASHLAND OIL INC

COLUMBUS, OH 43215
US

Emergency Phone: 606-324-1133

Info Phone: 514-889-3333

Cage: 60016

ASHLAND OIL INC ASHLAND CHEMICAL CO DIV

2219 KENT, WA 98031 US

Telephone: 614-790-3333/800-274-5263

Cage: 60016

LANDFILL IN ACCORDANCE WITH LOCAL, STATE

RTECS: 9999999ZZ

CONDITIONS. ENGINEERING OR ADMINSTRATIVE

RTECS: 9999999ZZ

MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR

RTECS: 9999999ZZ

ETHYL ALCOHOL; (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 92%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

METHYL ALCOHOL; (METHANOL)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 4%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-PENTANONE, 4-METHYL-; METHYL ISOBUTYL KETONE

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 2%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

NEVER GIVE ANYTHING BY MOUTH TO AN UNCON

RTECS: 9999999ZZ

AIR. IF BREATHING IS DIFFICULT, ADMIN O*2. IF BRTHG

RTECS: 9999999ZZ

AND GET MEDICAL ATTENTION.

RTECS: 9999999ZZ

STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: CAN CAUSE IRRITATION.
INHAL: EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND
RESPIRATORY IRRITATION AND CNS EFFECTS INCLUDING DIZZINESS,
WEAKNESS, FATIGUE, NAUSEA, HEADACHE AND POSSIBLE UNCONSCIOUSNESS.
INGEST: CAN CAUSE GI IRRIT, NAUSEA, VOMITING, AND DIARRHEA.
CHRONIC: OVEREXPOSURE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: THIS MATERIAL HAS APPARENTLY BEEN
FOUND TO CAUSE LIVER ABNORMALITIES, KIDNEY DAMAGE, EYE DAMAGE, LUNG
DAMAGE, SPLEEN DAMAGE, BRAIN DAMAGE AND NERVOUS SYSTEM DAMAGE IN
LAB ANIMALS. OVEREXP TO THIS MATL HAS BEEN SUGGESTED AS A CAUSE OF
LIVER ABNOMALITIES, AND EYE DAMAGE IN HUMANS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN:THORO WASH EXPOS AREA W/SOAP & H2O. REMOVE CONTAM CLTHG.
LAUNDER CONTAM CLTHG BEFORE RE-USE. REMOVE CONTAM SHOES PROMPTLY.
DISCARD SHOES SATURATED W/PROD. EYES:FLUSH W/LRG AMTS OF H2O FOR @
LST 1 5 MIN, LIFTING UPPER & LOWER LIDS OCCASIONALLY, GET MED ATTN.
INGEST:IMMED DRINK 2 GLASSES OF H2O & INDUCE VOMIT BY EITHER GIVING
IPECAC SYRUP/BY PLACING FINGER AT BACK OF THROAT. NEVER (ING 4)

Flash Point Method:TCC
Flash Point:51.0F,10.6C
Lower Limits:3.3 %
Upper Limits:20.7 %
Extinguishing Media:ALCOHOL FOAM OR CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE PRESSURE
SCBA AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG THE
GROUND OR MAY BE MOVED BY VENTILATION AND IGNITED BY PILOT LIGHTS,
OTHER FLAMES, SPARKS, HEATERS, SMOKING, (SUPP DATA)

Spill Release Procedures:SML SPILL:ABSORB LIQ ON PAPER, VERMICULITE,
FLOOR ABSORB/OTHER ABSORB MATL & TRANSFER TO HOOD. VENT AREA. LRG
SPILL: ELIM ALL IGNIT SOURCES. PERSONS NOT WEARING PROT EQUIP
SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP IS COMPLETED.
(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CNTNRS OF MATL MAY BE HAZ WHEN EMPTIED
SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES,(VAP,LIQ,SOLID) ALL HAZ
PREC GIVEN IN DATA SHEET MUST BE OBSERVED.
Other Precautions:CONTAINS METHANOL.

Respiratory Protection:IF WORKPLACE EXPOS LIMIT(S) OF PROD/ANY
COMPONENT IS EXCEEDED A NIOSH/MSHA APPROVED AIR SUPPLIED RESP IS
ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA
REGULATIONS ALSO PERMIT OTHER NIOSH/ M SHA APPRVD RESP UNDER
SPECIFIED (ING 10)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOS BELOW TLV(S).
Protective Gloves:RESISTANT GLOVES: NEOPRENE
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN
CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:ELEC MOTORS, STATIC DISCHARGE/ OTHER IGNIT SOURCES AT
LOCATIONS DISTANT FROM MATL HNDLG PT. NEVER USE WELD/CUTTING TORCH
ON/NEAR DRUM BECAUSE PROD CAN IGNITE EXPLOSIVELY. ALL FIVE GALLON
PAI LS & LARGER METAL CNTNRS INCLUDING TANKCARS & TANK TRUCKS
SHOULD BE GROUNDED AND/OR BONDED WHEN MATL IS TRANSFERRED.

HCC:F5
Boiling Pt:B.P. Text:171F,77C
Vapor Pres:47 @ 68 F
Vapor Density:1.6
Spec Gravity:0.794 @ 60F
Evaporation Rate & Reference:3.30 (BUTYL ACETATE=1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS: CARBON
DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC.

Waste Disposal Methods:SML SPILL:ALLOW VOLATILE PORTION TO EVAP IN
HOOD. ALLOW SUFF TIME FOR VAP TO COMPLETELY CLEAR HOOD DUCT WORK.
DISP OF REMAINING MATL I/A/W APPLIC FED/STATE/LOC REGS. LRG
SPILL:DESTROY BY LIQ INCINERAT ION. CONTAM ABSORB MAY BE DEPOSITED
IN A (ING 9)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.